Lutetium(III) chloride

Lutetium(III) chloride

chembox new
ImageFile =
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IUPACName = Lutetium(III) chloride
OtherNames = Lutetium chloride, lutetium trichloride
Section1 = Chembox Identifiers
Abbreviations =
CASNo = 10099-66-8
EINECS =
PubChem = 24868595
SMILES =
InChI =
RTECS = OK8400000
MeSHName =
ChEBI =
KEGG =
ATCCode_prefix =
ATCCode_suffix =
ATC_Supplemental =

Section2 = Chembox Properties
Formula = LuCl3
MolarMass = 281.325 g/mol
Appearance = colorless or white monoclinic crystals
Density = 3.98 g/cm³
MeltingPt = 905°CCitation
last = Lide
first = David R.
author-link =
last2 =
first2 =
author2-link =
publication-date =
date =
year = 1998
title = Handbook of Chemistry and Physics
edition = 87
volume =
series =
publication-place = Boca Raton, FL
place =
publisher = CRC Press
id =
isbn = 0849305942
doi =
oclc =
pages = 472
url = http://books.google.com/books?id=lFjg0L-uOxoC&pg=PT857&dq=%22Lutetium+chloride%22&as_brr=3&sig=ACfU3U0_ZGl9zHRByrDdVWXFijQHhwGxgg
accessdate = 2008-06-27
]
BoilingPt = sublimes above 750°Ccite web |url= http://202.114.88.54/g/web18/wangluo/webelements/webelements/compounds/text/lu/cl3lu1-10099668.html |title= Chemistry: Periodic Table: Lutetium: compound data (lutetium (III) chloride) |accessdate=2008-06-27 |publisher= WebElements |date= ]
Solubility = solubleCitation
last = Perry
first = Dale L.
author-link =
last2 = Phillips
first2 = Sidney L.
author2-link =
publication-date =
date =
year = 1995
title = Handbook of Inorganic Compounds
edition =
volume =
series =
publication-place =
place =
publisher = CRC Press
id =
isbn = 0849386713
doi =
oclc =
pages = 232
url = http://books.google.com/books?id=0fT4wfhF1AsC&pg=PA232&dq=%22Lutetium+chloride%22&as_brr=3&sig=ACfU3U2mqXQO8F0gO_VF2onDfcbXZuSx1Q
accessdate = 2008-06-27
]
SolubleOther =
Solvent =
pKa =
pKb =

Section7 = Chembox Hazards
ExternalMSDS =
EUClass =
EUIndex =
MainHazards = Xi (Irritant)
NFPA-H = 2
NFPA-F = 0
NFPA-R = 1
NFPA-O =
RPhrases = R36/37/38
SPhrases = S26, S36cite web |url= http://www.sigmaaldrich.com/catalog/search/ProductDetail/ALDRICH/450960 |title= 450960 Lutetium(III) chloride anhydrous, powder, 99.99% trace metals basis |accessdate=2008-06-27 |publisher= Sigma-Aldrich|date= ]
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Section8 = Chembox Related
OtherAnions = Lutetium(III) oxide
OtherCations = Scandium(III) chloride
Yttrium(III) chloride

Lutetium(III) chloride or lutetium trichloride is the chemical compound composed of lutetium and chlorine with the formula LuCl3. It forms hygroscopic white monoclinic crystals. Lutetium(III) chloride has the YCl3 (AlCl3) layer structure with octahedral lutetium ions. [ Wells A.F. (1984) "Structural Inorganic Chemistry" 5th edition Oxford Science Publications ISBN 0-19-855370-6 ]

Reactions

Pure lutetium metal can be produced from lutetium(III) chloride by heating it together with elemental calciumCitation
last = Patnaik
first = Pradyot
author-link =
last2 =
first2 =
author2-link =
publication-date =
date =
year = 2004
title = Handbook of Inorganic Chemicals
edition =
volume =
series =
publication-place = Amsterdam
place =
publisher = McGraw-Hill Professional
id =
isbn = 0070494398
doi =
oclc =
pages = 244
url = http://books.google.com/books?id=Xqj-TTzkvTEC&pg=PA510&dq=%22Lutetium+chloride%22&as_brr=3&sig=ACfU3U0_HAagr0jPQRltPbeKi7I0bIdNbA
accessdate = 2008-06-27
] ::2LuCl3 + 3Ca → 2Lu + 3CaCl2

References


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